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Temperature variation of the evolution of positive small air ions at constant relative humidity

The evolution of positive air ions is mathematically simulated considering 150 trace gases and more than a thousand ion-molecule reactions. The main attention is paid to the evolution of near-ground air ions in the age interval from 10 ms to 3 s …

Binary nucleation of water-sulfuric acid system: A reexamination of the classical hydrates interaction model

It is shown that the hydration correction for the free energy of cluster formation in the classical binary nucleation theory is not applicable for the thermodynamic data of the water-surface acid system commonly used in nucleation calculations. A new …

Bursts of intermediate ions in atmospheric air

The mobility spectrum of air ions has been measured at Tahkuse Observatory in Estonia for several years. The average concentration of intermediate ions with mobilities of 0.05-0.5 cm(2) V-1 s(-1) in atmospheric air is about 50 cm(-3). On the level of …

Air ion measurements as a source of information about atmospheric aerosols

The mobility spectra of air ions recorded in the course of routine atmospheric electric measurements contain information about atmospheric aerosols. The mobility spectrum of air ions is correlated with the size spectrum of aerosol particles. Two …

EVOLUTION OF NEGATIVE SMALL IONS AT ENHANCED IONIZATION

The paper deals with the modeling of the evolution(chemical kinetics) of tropospheric small ions for the case where the rate of ion generation is substantially above normal. Such types of situations can be found in the regions where because of either …

CHEMICAL-COMPOSITION OF SMALL ATMOSPHERIC IONS NEAR THE GROUND

The chemical composition of small ions has been studied by means of formal chemical kinetics. The model for negative ions contains 474 ion-molecular reactions, 143 ions, and 106 neutral compounds, and the model for positive ions contains 1044 …

MOBILITY SPECTRUM OF AIR IONS AT TAHKUSE-OBSERVATORY

Mobility spectra of air ions have been measured at a rural site in Estonia during several periods. The annual average mobility spectrum of natural small air ions is presented. The concentrations of two groups of air ions with mobilities 0.32-0.5 …

About the calibration of the electrical aerosol spectrometer